What does Chevron Make there?

Fuels are part of our lives. They are used to power cars, trucks, buses, trains, garden equipment, boats
and snowmobiles, as well as pumps, compressors and generators. We depend on fuels to move freight
and perform farm, construction and other labor. Unfortunately, their widespread use means we are
exposed to fuels and their emissions on a daily basis.
The California Environmental Protection Agency’s Office of Environmental Health Hazard Assessment
(OEHHA) assesses health risks from toxic substances, including those found in fuels. The American
Lung Association of California (ALAC) and its 15 local associations work to prevent lung disease and
promote lung health. Since 1904, the American Lung Association has been fighting lung disease through
education, community service, advocacy and research.
This fact sheet by OEHHA and the American Lung Association of California (ALAC) provides health
information on our two most commonly used motor vehicle fuels, gasoline and diesel fuel.
What harmful substances are found in gasoline and diesel fuel?
Gasoline and diesel fuels contain toxic substances that can enter the environment and cause adverse
health effects in people. Some of these substances, such as benzene, toluene and xylenes, are found in
crude oil and occur naturally in fuels and their vapors. Other substances, such as 1,3-butadiene and
formaldehyde, are formed in engines during combustion and are
only present in exhaust.
Other harmful pollutants found in engine exhaust include
particulate matter (known more commonly as soot), nitrogen
oxides, carbon monoxide, sulfur dioxide and various
hydrocarbons. Ozone, the major component of urban smog, is
formed when nitrogen oxides react in sunlight with
hydrocarbons.
Diesel exhaust is a particular health concern. There are
1.25 million diesel-fueled engines and vehicles operating in California. These diesel vehicles account for
only 2 percent of on-road motor vehicles in the state, but they produce 30 percent of the nitrogen oxides
and 60 percent of the particulate matter directly emitted from California motor vehicles. Diesel exhaust
also contains over 40 different substances identified by the California Air Resources Board (ARB) as toxic
air contaminants that may pose a threat to human health. The particulate matter in diesel exhaust has
been identified as a toxic air contaminant by ARB, and it has been linked to lung cancer.
How do fuels enter the environment?
The harmful substances in fuels can enter the environment in a number of ways throughout the entire
cycle of fuel production, manufacturing, transportation, storage, distribution and usage. Most commonly,
Fuels and Your Health
Toxic substances
occur naturally in
fuels and their
vapors
they come out the tailpipes of vehicles as exhaust or unburned fuel. Fuel vapors escape directly from
automobile engines and gas tanks, especially on hot days. They can also escape into the air during
refueling, or when liquid fuel evaporates from a spill. Fuels can enter lakes and reservoirs through
accidental spills or from motorized boats and personal watercraft. Fuels spilled on the ground or leaking
from fuel storage tanks can contaminate groundwater. Substances in airborne engine exhaust settle
directly onto water, soil and vegetation, or they can be washed down onto these surfaces when it rains.
Even groundwater can be contaminated in these ways. Also, fuel components are released into the
environment during oil drilling, refining and transportation.
How are people exposed to fuels?
Just breathing the air exposes people to fuel components, especially in urban areas. People are exposed to
gasoline and diesel exhaust when they drive or ride in a vehicle, jog or bike along roads or park in a public
garage. Motorists are further exposed to gasoline vapors when they fill up their vehicle’s fuel tank.
People who work in or live near freeways, refineries, chemical plants, loading and storage facilities or
other places that handle crude oil and petroleum products may be exposed to higher levels of fuel
components than the general public and face higher health risks.
What health effects are associated with exposure to fuels?
Breathing gasoline and diesel vapors can irritate the nose and throat and cause headaches, dizziness,
nausea, vomiting and confusion. Of course, most people are not exposed to high enough levels of fuels
to become ill in this manner. However, we are all exposed to lower levels of fuel components throughout
our lives. This lifelong exposure can increase the risk of adverse
health effects.
Both liquid gasoline and motor vehicle exhaust contain
chemicals that can cause cancer. Benzene, a fundamental
component of gasoline and diesel fuel as well as vehicle exhaust,
causes cancer in humans. Gasoline exhaust also contains
cancer-causing 1,3-butadiene, formaldehyde and acetaldehyde.
Diesel exhaust contains several dozen toxic substances and
scientific studies have shown that workers exposed to diesel
exhaust are more likely to develop lung cancer. Long-term exposure to particles in diesel exhaust poses
the highest cancer risk of any toxic air contaminant evaluated by OEHHA. ARB estimates that about
70 percent of the cancer risk that the average Californian faces from breathing toxic air pollutants stems
from diesel exhaust particles. The microscopic particles making up diesel exhaust particulate matter are
less than one-fifth the thickness of a human hair. They are small enough to penetrate deep into the lungs,
where they can contribute to respiratory disease.
Gasoline and diesel exhausts contain nitrogen oxides, carbon monoxide and sulfur dioxide. Nitrogen
oxides can damage lung tissue, lower the body’s resistance to respiratory infection and worsen chronic
lung diseases such as asthma. As mentioned earlier, nitrogen oxides react in the atmosphere with
hydrocarbons to form ozone, the major component of urban smog. Ozone is a strong irritant to the eyes
and respiratory tract. It can make respiratory problems worse for people who already have asthma and
other respiratory diseases. Children, senior citizens and people with chronic lung disease, such as Chronic
Obstructive Pulmonary Disease (COPD), are especially sensitive to ozone. Ozone also hurts the lungs of
healthy people who exercise outdoors when ozone levels are high.
Both liquid gasoline
and motor vehicle
exhaust contain
chemicals that can
cause cancer
Carbon monoxide is a colorless, odorless gas that limits the blood’s ability to transport oxygen to body
tissues. Its presence in the body places a strain on people who already have cardiac or respiratory
diseases, as well as pregnant women and the elderly.
MTBE
Another concern about gasoline is methyl tertiary butyl ether, or MTBE, which originally was used in
gasoline in small amounts to reduce engine knocking. Beginning in the mid-1990s, more MTBE was
added to make gasoline burn cleaner and produce less air pollution. MTBE is present in gasoline vapors
and in the exhaust.
Regulatory agencies for years have required the
monitoring of drinking-water wells for benzene and
other gasoline components that can enter groundwater
from leaking underground tanks. As its use became
more widespread in the 1990s, MTBE also began to
show up in California drinking water wells that were
near leaking underground tanks. Bacteria do not break MTBE down as readily as they do benzene, so
MTBE will stay in the water longer. MTBE is also more difficult and expensive to remove than benzene.
Even at very low concentrations, MTBE has an unpleasant taste and odor that renders drinking water
unusable.
Although not as toxic as benzene, MTBE has been shown to cause cancer in certain laboratory animals
and may cause cancer in humans. Because of concerns about MTBE in California’s drinking water
supplies and its general impact on public health and the environment, Governor Gray Davis ordered the
removal of MTBE from California’s gasoline by the end of 2002.
Concerns about MTBE also prompted legislation that requires the study of potential health impacts prior
to the adoption of any new state gasoline regulations that are intended to improve air quality. OEHHA is
developing methods to study the risks that could occur throughout the entire “life cycle” of a fuel, from
its production, storage, transportation, dispensing and use, through its recycling and disposal.
What has been done to reduce the public’s risk from exposure to fuels?
Over the past two decades, many significant improvements have made both fuels and engines cleaner and
far less polluting. Highly toxic lead was removed from gasoline. ARB has established stricter emission
standards for gasoline- and diesel-fueled cars, trucks and buses. During the 1990s, ARB required the
reformulation of gasoline and diesel fuel to reduce smog-forming and toxic emissions. Health
assessments developed by OEHHA have guided ARB in its decisions. Thanks to these changes, pollution
levels in many areas of California have decreased substantially in recent years. New vehicle emission
standards, which will be phased in during the next several years, are intended to further reduce unhealthy
levels of air pollution. However, dramatically rising vehicle usage in California presents a continual
challenge to regulatory control efforts and threatens to erode the air quality gains that have been made.
Recent emission standards have reached beyond “traditional” motor vehicles to include motorcycles;
outboard boat engines; lawn and garden equipment; and farm, construction and utility equipment. These
new requirements will help to reduce harmful emissions from these formerly unregulated engines, which
can produce many times the pollution of a late-model automobile.
Pollutants in vehicle
exhaust can irritate or
damage the lungs
To protect water supplies from leaking underground fuel storage tanks, federal and state regulations
require that old, single-walled tanks be replaced with new, double-lined tanks with leak detectors. The
State Water Resources Control Board and nine regional water quality control boards oversee these
regulations. In addition, ARB standards for new outboard engines and personal watercraft intended to
reduce emissions will reduce fuel releases into water. There are even requirements for new portable gas
cans that will help reduce accidental spills.
What more must be done to protect public health?
Despite all of the progress made so far, more than 90 percent of Californians still breathe unhealthy air.
The reason is mostly due to motor vehicles. The number of vehicles on the road and the miles they travel
continue to grow. Even as older vehicles are replaced with newer, less polluting ones, our progress
towards clean air is being eroded by growth in vehicle
travel.
California is continuing to take the lead in developing
cleaner fuels and setting stricter emission standards for
gasoline and diesel-fueled vehicles and other engines.
These programs will help to reduce people’s exposure to
fuel toxics and smog.
State law requires measures to reduce the public’s risk from exposure to toxic air contaminants, including
diesel exhaust. ARB has approved a plan to reduce particle emissions from diesel engines by 85 percent
by 2020 through measures such as low-sulfur diesel fuel, equipping diesel engines with particulate traps
and the use of alternative fuels.
Alternative fuels include electricity, natural gas, fuel cells, ethanol, methanol and propane. All of them
have the potential to produce less air pollution than gasoline or diesel fuel. Toxic and smog-forming
emissions from electricity, natural gas and other alternative fuel vehicles can be dramatically lower than
emissions from conventional vehicles. As a result of ARB regulations, major vehicle manufacturers will
be producing increasing numbers of vehicles that run on alternative fuels.
What can I do to help?
Anything you do to reduce the amount of fuel you use will help protect the environment. Bicycle or walk
instead of driving. Try riding public transit, carpooling or vanpooling instead of driving alone. Take
advantage of any “telework” (work at home) programs your employer may have. If you drive, keep your
vehicle well tuned. A properly maintained vehicle contributes less to air pollution and saves you money
on gas. Run all your errands at once because a warm engine pollutes less. When refueling your vehicle,
don’t top off at the gas pump. If the dispensing nozzle is equipped with a hold-open latch, use it and
move upwind of the fumes. Close your vehicle’s windows to protect any passengers.
When shopping for your next car, look for the most efficient, lowest polluting model or even a zeropolluting
electric car. ARB’s Web site has a “Clean Car Buyers Guide” with information on low-polluting
vehicles. If you must drive on days with unhealthy air, drive your newest car. Newer cars generally
pollute less than older models.
California plans to reduce
particle emissions from
diesel engines 85 percent
by 2020
When using motorized watercraft, prevent leaks and spills of fuel and oil by properly maintaining the
engines, lines and hoses. Don’t let the tank overflow and use an oil-only absorbent to clean up any drips.
When buying a new outboard engine or personal watercraft, look for engine labels certifying that the
equipment meets California’s low-emission standards.
Use electric lawn and garden equipment when possible. Reduce, re-use and recycle as much as possible.
It takes fuel to produce and ship new goods.
For more information on how you can reduce air pollution, contact the American Lung Association at the
phone numbers or Web site address listed below.
For further information
Office of Environmental Health Hazard Assessment
1001 I Street, P.O. Box 4010, Sacramento, CA 95812-4010
(916) 324-7572
http://www.oehha.ca.gov
American Lung Association of California
921 11th Street, Suite 700, Sacramento, CA 95814
(916) 442-4446
For your local office, call (800) LUNG-USA
http://www.californialung.org
Air Resources Board
1001 I Street, Sacramento, CA 95814
(800) 363-7664
http://www.arb.ca.gov
State Water Resources Control Board
Division of Clean Water Programs, 1001 I Street, Sacramento, CA 95814
(916) 341-5254
http://www.swrcb.ca.gov
The energy challenge facing California is real. Every Californian needs to take immediate action to reduce energy consumption. For a list of simple
ways you can reduce demand and cut your energy costs, see OEHHA’s web site at http://www.oehha.ca.gov/public_info.html.

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